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Our ability to reconstruct the crystallization history of a given accessory mineral (i.e., geochronometers such as zircon, titanite, monazite, etc.)—and thus the geologic processes of its host—has increased severalfold over the past few decades; primarily through advances in precision, concurrent chemical analysis, throughput, and spatial resolution. In this contribution, we present a methodology that takes these advances a step further through the rapid characterization of a large number of accessory minerals at micron-scale resolution via laser-ablation inductively coupled plasma mass spectrometry. Our analytical setup employs an ultrafast washout laser (~1 ms; Element Scientific Laser) that can send individual, <5um ablation pulses to either one or both of two instruments: a Nu Plasma 3D mulitcollector ICP-MS and a Nu Vitesse time-of-flight ICP-MS. Because either ICP-MS can measure at the sub-ms timescale, every pulse can be analyzed at 100’s of Hz; 1D, 2D, or 3D analysis is possible, and data can be processed in a matter of minutes and hours, instead of days or weeks. We highlight the advantages of this methodology through examples of accessory phases in complex plutonic rocks and high-grade metamorphic terranes. 

Abstract Ultrahigh-temperature metamorphism (UHTM) is important for the evolution and long-term stability of continental crust. The Anosyen domain in southeastern Madagascar is a well-preserved UHTM terrane that formed during the amalgamation of Gondwana. The heat source(s) required to reach peak conditions is(are) a matter of debate. One potential cause of extreme crustal heating is the intrusion of mantle-derived melts into the crust. Foundering of the mantle lithosphere can also lead to increased heat flow. To assess the role of these heating mechanisms, we measured zircon δ18O, εHf(t) compositions, and U-Pb dates for plutonic rocks in the midcrustal UHTM domain. Our results indicate that pluton emplacement predated UHTM by as much as 40 m.y. and that all zircons have crustal O and Hf isotopic compositions. We propose that mantle lithosphere foundering caused melting in the lower crust, producing the magmas responsible for plutonism during the early stages of orogenesis. Prolonged conductive heating of the crust—combined with above-average radiogenic heating—may explain why UHTM occurred ∼40 m.y. after foundering. This suggests that foundering of the mantle lithosphere can swiftly lead to partial melting in the lower crust, as well as protracted heating of the middle crust that culminates tens of millions of years later. 

Abstract The northern North American Cordilleran margin has been active for >200 million years, as recorded by punctuated phases of crustal growth and deformation. Accretion of the exotic Wrangellia Composite Terrane (Insular Belt) is considered the largest addition of juvenile crust to the Cordilleran margin, though margin-parallel translation during the Cenozoic has obscured much of the accretionary history. Three zones of inverted metamorphism spatially correspond to the Insular–North American suture zone from north to south: (1) Clearwater Mountains; (2) Kluane Lake; and (3) Coast Mountains, each preserving kinematics indicative of thrusting of North American–derived rocks over Insular-derived assemblages. We performed in situ monazite petrochronology on samples collected across strike in both the Clearwater and Coast Mountain regions. New and recently published data from these three metamorphic belts indicate that thrust-sense deformation accompanied the formation of inverted metamorphic isograds from 72 to 56 Ma. We leverage recent estimates of Denali fault offset to reconstruct a >1000-km-long zone of inverted metamorphism and interpret it as the Insular–North America terminal suture. 

Petrologic and geochronologic data for metapelitic lower crustal xenoliths from New Mexico (USA) and Chihuahua (Mexico) states provide evidence for both a magmatic and collisional component to the enigmatic Mesoproterozoic Picuris orogeny. These garnet-sillimanite-bearing metapelites are found within the southern Rio Grande rift at Kilbourne Hole and Potrillo Maar in southern New Mexico and northern Chihuahua. Geothermobarometry and rutile with Quaternary U-Pb dates indicate equilibration in the local lower crust, which is actively undergoing ultra-high temperature (UHT) metamorphism (Cipar et al., 2020). The samples contain older detrital zircons dating back to the Paleoproterozoic, marking their deposition at the surface. Coupled zircon U-Pb dates and trace-element ratios (e.g., Gd/Yb) show a clear transition from oscillatory-zoned, low-Gd/Yb detrital magmatic zircon to featureless, high-Gd/Yb metamorphic zircon between 1500 and 1400 Ma, marking the transition from subduction to collision during this period. Metamorphic zircon and monazite grew in two major intervals. The first, between ca. 1450 and 1350 Ma, documents the journey of the sediments to depth within the orogen and provides evidence of extended Mesoproterozoic metamorphism in the region. The second corresponds with UHT metamorphism that commenced at ca. 32 Ma and is associated with the Rio Grande rift. Whereas nearly all garnets are homogeneous in both major and trace elements, a single garnet from one sample has a core defined by abundant quartz and acicular sillimanite inclusions. The core and rim of this garnet is homogeneous in major and most trace elements, but the rim is enriched in the slowest diffusing elements, Zr and Hf, which likely indicates rim growth at higher temperatures. We interpret the garnet core to have grown at the time of emplacement of the sediments into the lower crust. Because this occurred in the sillimanite stability field and because the metamorphic zircon and monazite all have negative Eu anomalies, indicating their equilibration with feldspar (stable at depths of <45 km), we conclude that the sediments were not emplaced via subduction and/or relamination of forearc sediments, but were instead metamorphosed under warmer, shallower conditions in an orogenic setting. Collectively, the data point to a collisional orogen during the inferred timing of the Picuris orogeny. These samples may therefore define the location of the Picuris suture zone, a key feature of this orogenic event. 

Porosity generated during fluid–rock reaction can facilitate fluid transport and metasomatism in low permeability high-pressure metamorphic rocks. Evidence for reaction-induced porosity is found in an eclogite-facies clinopyroxene + apatite vein in an undeformed eclogitized Fe–Ti metagabbro from the Monviso Ophiolite (W. Alps) with a distinct garnet-rich selvage. Vein-forming fluids were sourced from adjacent metagabbros and reaction with the host rock removed Ca and P from the selvage and added Fe, REE, Pb and Cr. Textures at the selvage–host rock interface and in the host rock record local heterogeneity in reactivity and porosity during metasomatism linked to variable initial lawsonite abundance. These features reflect a hierarchy of pervasive-to-channelized porosity structures that facilitated widespread metasomatism of the host rock. Development of this metasomatic system in response to locally derived fluids suggests large-scale externally derived fluid transport is not required to drive extensive fluid–rock exchange. The production of porosity during metasomatic reactions could be important in facilitating further fluid–rock reaction and fluid transport in subducting slabs where permeability is low. 

In the last two decades, crustal channel and escape flow, wherein long-wavelength ductile flow of lower crustal material transports mass and heat out of the collision zone, have remained among the most impactful ideas proposed to explain shortening accommodation in continental collisions. In the Inner Piedmont (IP), southern Appalachians, channel and escape flow have been previously proposed for the Devonian-Mississippian Neoacadian orogeny, and the deep exhumational level of the IP relative to other orogens in which channel flow has been proposed makes it ideal for testing the channel and escape flow models. In the IP channel flow model, the Brevard fault zone (BFZ) footwall is interpreted to buttress orogen-normal crustal flow of the hot IP in northwestern North Carolina and drive escape flow to the southwest. However, the polymetamorphic and deformational history of the southern Appalachians has made it difficult to isolate the spatial and temporal extent of thermal and deformational events driving flow of the interpreted channel. To address this, we use in situ laser ablation split stream monazite (Mz) U-Pb geochronology and geochemistry coupled with quantitative P-T data to define the extent and conditions of Paleozoic metamorphic events in the southern Appalachians of North Carolina. In this area, northwest of the BFZ, Mz dates indicate mostly Taconic (~462 Ma) and minor Neoacadian metamorphism (~368 Ma) whereas IP data show Neoacadian metamorphism (~363–330 Ma) with no Taconic ages. IP Mz also records a transition over time from HREE-poor to HREE-rich compositions, indicating Mz growth associated with both garnet growth and breakdown, respectively. This, along with diffuse chemical profiles and resorption textures in garnet, suggests that IP Mz records prograde to retrograde metamorphism. Furthermore, P-T estimates from the eastern Blue Ridge of northwestern NC are 5–9 kbar and 565–730 °C, whereas peak Neoacadian metamorphism in the IP core reached 5–8 kbar and 750–850 °C. We interpret this to indicate that the BFZ footwall acted as both a thermal and rheological boundary in northwestern NC during Neoacadian metamorphism, supporting earlier interpretations. Future work will assess the timing and conditions of metamorphism further south into the Blue Ridge and IP of South Carolina, Georgia, and Alabama.